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超分子手性的研究对于促进生命科学﹑材料化学等相关学科的发展具有非常重要的价值,已发展成为当前手性科学领域的热点之一.动态的智能超分子手性材料具有良好的刺激响应性,其组装结构和功能特性随外界环境的改变而发生敏感的变化.本文介绍了超分子手性的组装原理,详细阐述了光、温度、氧化还原、p H、溶剂、超声、离子、浓度等刺激对超分子手性的动态调控,着重综述了超分子手性在手性模板、手性开关、手性液晶、手性催化、手性传感、圆偏振发光材料及生物医用材料等方面的功能性研究.这些成果为超分子手性的研究领域拓展了新的发展空间,为手性科学问题的研究提供了新思路和新方法.
The research on supramolecular chirality has great value in promoting the development of life sciences, materials chemistry and other related disciplines and has become one of the hot topics in the field of chiral science.The dynamic intelligent supramolecular chiral materials have good stimulus response The assembly structure and functional properties of the supramolecular complexes are sensitive to the changes of the external environment.In this paper, the assembly principle of supramolecular chirality is introduced, and the principles of light, temperature, redox, p H, solvent, ultrasonic, ion, Such as chiral template, chiral switch, chiral liquid crystal, chiral catalysis, chiral sensing, circularly polarized luminescent materials and biomedical materials, are reviewed emphatically Which has opened up a new development space for the research field of supramolecular chirality and provided new ideas and new methods for the study of chiral science.