用室温固相反应合成了［Ｃｕ（８－Ｑ）２（ｐｈｅｎ）］·Ｈ２Ｏ 及［Ｃｕ（ＮＣＳ）２（ｐｈｅｎ）２］·Ｈ２Ｏ 两个三元混配化合物。室温下［Ｃｕ（Ａｃ）２（Ｈ２Ｏ）］与邻菲?啉固体几乎不发生反应，但加入第二配体８－羟基喹啉及ＫＳＣＮ，反应几乎立即发生。ＸＲＤ、ＩＲ谱及元素分析结果表明：第二配体的加入并不仅仅促进［Ｃｕ（Ａｃ）２（Ｈ２Ｏ）］与第一配体的反应，它同时也参与反应，形成了三元混配化合物。用室温固相反应合成上述两个三元混配化合物尚未见报道 Cu (8-Q) 2 (phen)] · H2O and [Cu (NCS) 2 (phen) 2] · H2O were synthesized by solid-state reaction at room temperature. At room temperature [Cu (Ac) 2 (H2O)] hardly reacts with o-phenanthroline solid, but with the addition of the second ligands, 8-hydroxyquinoline and KSCN, the reaction occurs almost immediately. The results of XRD, IR and elemental analysis show that the addition of the second ligand does not only promote the reaction of [Cu (Ac) 2 (H2O)] with the first ligand, but also participates in the reaction to form a ternary mixed Compound. The synthesis of the above two ternary compounds by solid-phase reaction at room temperature has not been reported yet