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阳极溶出伏安法(简称ASV),又称逆向极谱法或阳极溶出极谱法等。由Zbinder于1931年用于实际测定。后来随着悬汞电极和汞膜电极的应用,尤其是由于高纯材料分析和环境监测的需要,ASV法的应用日趋广泛。到目前为止,已有为数颇多的综述和专著。本文拟就方法原理和特点、电极材料和工作电极,共存元素的影响及其消除和有色金属材料分析中的应用作一综述。
Anodic stripping voltammetry (referred to as ASV), also known as reverse polarography or anodic dissolution polarography and so on. By Zbinder in 1931 for the actual determination. Later, with the application of hanging mercury electrode and mercury film electrode, especially because of the need of high purity material analysis and environmental monitoring, ASV method is widely used. To date, there have been numerous reviews and monographs. This paper reviews the principle and characteristics of the method, the influence of the electrode material and the working electrode, the co-existing elements and their elimination and the application in the analysis of non-ferrous metal materials.