Coopper carboxylate complexes play an important role in catalysing the enzymatic activi-ties[1— 4] ,and the phosphate has an especial use in DNA recognition[5] .Indeed the reportabout copper carboxylate complexes with phosphate ligands is rare. A chain s Coopper carboxylate complexes play an important role in catalysing the enzymatic activi- ties [1- 4], and the phosphate has an especial use in DNA recognition [5] .dede the reportabout copper carboxylate complexes with phosphate ligands is rare.