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气液色谱法是研究酸碱相互作用热力学性质的有效方法之一。文献[1～3]利用气液色谱法测量了Ni(THDD)_2、Ni[(C_8H_(17)O)_2PS_2]_2与含氮有机碱加合反应的平衡常数、标准焓变和标准熵变值,得到了与光谱法相一致的结果。作为酸碱加合反应研究的一部分,本文测定了Ni[(C_8H_(17)O)_2PS_2]_2与醛类化合物的热力学参数。
Gas-liquid chromatography is one of the effective methods to study the thermodynamic properties of acid-base interaction. In literature [1-3], the equilibrium constant, standard enthalpy change and standard entropy change of Ni (THDD) _2 and Ni [(C_8H_ (17) O) _2PS_2] _2 adduct with nitrogenous organic base were measured by gas- Value, the result is consistent with the spectrometry. As part of the acid-base adduct reaction, the thermodynamic parameters of Ni [(C_8H_ (17) O) _2PS_2] _2 and aldehydes were determined.