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A mononuclear manganese complex [Mn(2,2′-bipy)(H2O)4]·(m-phth) (2,2′-bipy=2,2′-bipyridine, m-phth=isophthalate) has been synthesized by hydrothermal methods. The crystal structure was determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pnna with a=0.766 8(8) nm, b=2.050 2(2) nm, c=1.247 0(13) nm, V=1.960 4(4) nm3, Z=4, Mr=447.30, Dc=1.376 g·cm-3, μ=0.722 mm-1, F(000)=924, Rint=0.027 0, R=0.028 0 and wR=0.075 5. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from 2,2′-bipyradine and four oxygen atoms from water molecules, completing an octahedral coordination geometry. The isophthalate molecules are included in the lattice and connected to Mn(2,2′-bipy)(H2O)4 by hydrogen bonding interactions to form a three-dimensional supramolecular structure. CCDC:286965.
A mononuclear manganese complex [Mn (2,2’-bipy) (H2O) 4] (m-phth) (2,2’-bipy = 2,2’-bipyridine, m- phth = isophthalate) has been synthesized by The crystal structure was determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pnna with a = 0.766 8 (8) nm, b = 2.050 2 (2) nm, c = 1.247 0 ( 13000 nm, V = 1.960 4 (4) nm3, Z = 4, Mr = 447.30, Dc = 1.376 g · cm -3, μ = 0.722 mm -1, F (000) = 924, Rint = = 0.028 0 and wR = 0.075 5. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from 2,2’-bipyradine and four oxygen atoms from water molecules, completing an octahedral coordination geometry. The isophthalate molecules are included in the lattice and connected to Mn (2,2’-bipy) (H2O) 4 by hydrogen bonding interactions to form a three-dimensional supramolecular structure. CCDC: 286965.