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合成了水杨醛缩牛磺酸席夫碱合铜配合物,研究了该配合物分别在阴离子表面活性剂十二烷基苯磺酸钠(SDBS)、阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)和非离子表面活性剂辛基酚聚氧乙烯醚(OP-10)的胶束中对H2O2分解的催化性能,探讨了pH、过氧化氢浓度对催化性能的影响。结果表明:该配合物在阳离子胶束中对H2O2的分解具有快速催化作用,其催化速率远远高于铜离子本身的催化速率,而且在碱性介质中催化速率明显提高;非离子和阴离子表面活性剂胶束对配合物的催化有禁阻作用。
Synthesis of salicylaldehyde taurine Schiff base copper complexes, the study of the complex were in the anionic surfactant sodium dodecyl benzene sulfonate (SDBS), cationic surfactant cetyl trimethyl (CTAB) and non-ionic surfactant octylphenol polyoxyethylene ether (OP-10) on the catalytic performance of H2O2 decomposition, and discussed the effect of pH and hydrogen peroxide concentration on the catalytic performance. The results show that the complex has a rapid catalytic effect on the decomposition of H2O2 in cationic micelles, and its catalytic rate is much higher than that of copper ion itself, and the catalytic rate in alkaline medium is obviously increased. The nonionic and anionic surfaces Active micelles forbid the catalytic role of the complex.