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The title compound, {Mn(H2O)4(VO)2(PO4)2}n 1, was synthesized by the hydro- thermal reaction of Mn(OAc)2, Na2VO3 and H3PO4 in aqueous solution and its crystal structure was determined by X-ray single-crystal analysis. Crystallographic data for 1: H4MnO14P2V2, tetragonal system, space group I4/mmm, a = 6.251(3), c = 13.410(9) ?, Mr = 446.79, V = 524.0(5) ?3, Z = 2, F(000) = 434, μ = 3.320 mm-1, Dc = 2.832 g/cm3, the final R = 0.0577 for 163 observed reflections (I > 2σ(I)). X-ray crystal structure analysis shows that the vanadium phosphorous oxide layers are further connected by MnII(H2O)4 cations to form a three-dimensional network.
The title compound, {Mn (H2O) 4 (VO) 2 (PO4) 2} n1, was synthesized by the hydro-thermal reaction of Mn (OAc) 2, Na2VO3 and H3PO4 in aqueous solution and its crystal structure was determined by Crystallographic data for 1: H4MnO14P2V2, tetragonal system, space group I4 / mmm, a = 6.251 (3), c = 13.410 (9)?, Mr = 446.79, V = 524.0 X-ray crystal structure (I> 2σ (I)), Z = 2, F (000) = 434, μ = 3.320 mm- 1, Dc = 2.832 g / cm3, the final R = 0.0577 for 163 observed reflections analysis shows that the vanadium phosphorous oxide layers are further connected by MnII (H2O) 4 cations to form a three-dimensional network.