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A polyethylene glycol (PEG)-supported NADH model as a novel organic reductant was designed and synthesized. The reductions of various α,β-unsaturated ketones by the PEG-supported NADH model were examined,and the results showed that the reductions completely and quickly proceed with no catalyst at ambient temperature. The main advantages of this liquid-like PEG-supported NADH model are easy workup,and an optimal potential for recycling use and solvent-free for use in reactions.
A polyethylene glycol (PEG) -supported NADH model as a novel organic reductant was designed and synthesized. The reductions of various α, β-unsaturated ketones by the PEG-supported NADH model were examined, and the results showed that the reductions completely and quickly proceed with no catalyst at ambient temperature. The main advantages of this liquid-like PEG-supported NADH model are easy workup, and an optimal potential for recycling use and solvent-free for use in reactions.