The First Total Synthesis of Triprenylquinone and Hydroquinones

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:blnxy325
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First total synthesis of triprenylquinone and hydroquinones, three naturally occurring compound 1, 2 and (±) 3, have been achieved from readily available 2-bromo-5-methyl-1, 4-dimethoxybenzene 4 and geranyl bromide. The triprenylquinone and hydroquinones precursor were readily prepared with use of a Julia reaction. First total synthesis of triprenylquinone and hydroquinones, three naturally occurring compounds 1, 2 and (±) 3, have been achieved conveniently from readily available 2-bromo-5-methyl-1, 4-dimethoxybenzene 4 and geranyl bromide. The triprenylquinone and hydroquinones precursor were prepared prepared with use of a Julia reaction.
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