二维碳石墨炔研究进展与展望

来源 :科学通报 | 被引量 : 0次 | 上传用户:LUEYONGS
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
石墨炔是由二炔键将6个苯环共轭连接形成的具有二维平面网络结构的全碳分子,其sp与sp2杂化态的成键方式决定了它的独特分子构型,使其具有优异的电学、光学和光电性能,在信息技术、电子、能源、催化以及光电等领域具有潜在、重要的应用前景.自2010年被成功合成后,石墨炔的研究吸引了不同领域科学家的广泛关注,已经在石墨炔的理论预测、合成方法及应用方面开展了大量研究工作,使石墨炔研究稳定地进入了一个较快发展时期,并正在形成了一个新的研究热点和领域.本文总结了石墨炔近3年来的最新研究成果,重点描述了石墨炔的电学、电化学和催化性质及功能化等方面的研究进展,并对未来的研究进行了展望. Graphite alkyne is a two-dimensional planar network composed of two benzene rings connected by two acetylenic bonds. The bonding mode of sp and sp2 hybrid states determines its unique molecular configuration, Has excellent potential for electrical, optical and optoelectronic applications in information technology, electronics, energy, catalysis and optoelectronics, etc. Since its successful synthesis in 2010, the research of graphite alkyne has attracted a wide range of scientists from different fields Concerned, a great deal of research work has been carried out on the theoretical prediction, synthesis methods and applications of graphite alkynes, making the study of graphite alkynes enter a period of rapid development steadily and a new research hot spot and field are being formed.This paper summarizes Graphite acetylene recent 3 years of recent research results, focusing on the graphitization of the electrical, electrochemical and catalytic properties and functional aspects of research, and future research prospects.
其他文献
广西东兰县武篆镇中和圩前,耸立着一座六角红塔魁星楼,至今已近百年。前人称为“文明楼”,今被定为广西重点文物保护单位。  魁星楼是清光绪年间所建,由地方贤达父老热忱囊助,献策献计,士农工商各界慷慨解囊捐助,不数月即捐获白银7千元之巨款,乃于光绪三十一年三月兴土建筑,至三十三年四月落成。魁星楼为木石结构攒尖式六角塔,底宽7米,高17.5米,三层飞檐,内分四层;楼身外面刻画花鸟鱼凤,楼顶角脊雕置六具蛟龙