Generation, morphology, and distribution of authigenic minerals directly reflect sedimentary environment and material sources. Surface sediments were collected from the western Gulf of Thailand during 2011–2012, and 159 samples were analyzed to determine detrital minerals. Authigenic minerals, including siderite, pyrite, and glauconite, are abundant whereas secondary minerals, such as chlorite and limonite, are distributed widely in the study area. Siderite has a maximum content of 19.98 g/kg and appears in three types from nearshore to continental shelf, showing the process of forming-maturity-oxidation. In this process, the Mn O content in siderite decreases, but Fe_2O_3 and Mg O content increase. Colorless or transparent siderite pellets are fresh grains generated within a short time and widely distributed throughout the region; high content appears in coastal area where river inputs are discharged. Translucent cemented double pellets appearing light yellow to red are mature grains; high content is observed in the central shelf. Red-brown opaque granular pellets are oxidized grains,which are concentrated in the eastern gulf. Pyrite is mostly distributed in the central continental shelf with an approximately north–south strip. Pyrite are mainly observed in foraminifera shell and distributed in clayey silt sediments, which is similar to that in the Yangtze River mouth and the Yellow Sea. The pyrite in the gulf is deduced from genetic types associated with sulfate reduction and organic matter decomposition. Majority of glauconite are granular with few laminar. Glauconite is concentrated in the northern and southern parts within the boundary of 9.5° to 10.5°N and is affected by river input diffusion. The distribution of glauconite is closely correlated with that of chlorite and plagioclase, indicating that glauconite is possibly derived from altered products of chlorite and plagioclase. The K_2O content of glauconite is low or absent, indicating its short formation time. Generation, morphology, and distribution of authigenic minerals directly reflect sedimentary environment and material sources. Surface sediments were collected from the western Gulf of Thailand during 2011-2012, and 159 samples were analyzed to determine detrital minerals. Authigenic minerals, including siderite, pyrite, and glauconite, are abundant with secondary minerals, such as chlorite and limonite, are distributed widely in the study area. Siderite has a maximum content of 19.98 g / kg and appears in three types from nearshore to continental shelf, showing the process of forming- maturity-oxidation. In this process, the Mn O content in siderite decreases, but Fe_2O_3 and MgO content increase. Colorless or transparent siderite pellets are fresh grains generated within a short time and widely distributed throughout the region; high content appears in the coastal area where river inputs are discharged. Translucent cemented double pellets appearing light yellow to red are mature grain High content is observed in the central shelf. Red-brown opaque granular pellets are oxidized grains, which are concentrated in the eastern gulf. Pyrite is mostly distributed in the central continental shelf with an approximately north-south strip. in foraminifera shell and distributed in clayey silt sediments, which is similar to that in the Yangtze River mouth and the Yellow Sea. The pyrite in the gulf is deduced from genetic types associated with sulfate reduction and organic matter decomposition. Majority of glauconite are granular with The distribution of glauconite is concentrated in the northern and southern parts within the boundary of 9.5 ° to 10.5 ° N and is affected by the river input diffusion. The distribution of glauconite is closely correlated with that of chlorite and plagioclase, indicating that glauconite is possibly derived from altered products of chlorite and plagioclase. The K_2O content of glauconite is low or absent, indicating its short formance tion time.