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On the basis of the C_C coupling reactions of dibenzo[fg,op]naphthacene bistriflate, which was obtained by the condensation of phenylacetates with 4-aryl-2,6-bis(2-bromo-4-methoxy-phenyl) pyrylium salts followed by palladium-catalyzed dehydrohalogenation, three shape-persistent macrocycles with dibenzonaphthacene corner pieces, a nanometer interior void, and intraanular oligoalkyl side groups were synthesized by the oxidative cyclization of the corresponding bisacetylenes under high-dilution conditions. Their thermotropic liquid crystalline properties were investigated by using polarizing microscopy and differential scanning calorimetry. All the three compounds showed nematic mesophases and belonged to discotic liquid crystals with inverted topology.
On the basis of the C_C coupling reactions of dibenzo [fg, op] naphthacene bistriflate, which was obtained by the condensation of phenylacetates with 4-aryl-2,6-bis (2-bromo-4-methoxy- phenyl) pyrylium salts followed by palladium-catalyzed dehydrohalogenation, three shape-persistent macrocycles with dibenzonaphthalene corner pieces, a nanometer interior void, and intraanular oligoalkyl side groups were synthesized by the oxidative cyclization of the corresponding bisacetylenes under high-dilution conditions. Their thermotropic liquid crystalline properties were investigated by using the polarizing microscopy and differential scanning calorimetry. All the three compounds showed nematic mesophases and belonged to discotic liquid crystals with inverted topology.