合成了氰化铜(工)配位聚合物(CuCN)n,并进行了X-射线单晶衍射结构测试.该化合物为波浪型层状结构,包含12元Cu6 (CN)6环,且没有额外的配体配位,同时环内存在质子化的吗啉阳离子,其扮演着模版和抗衡离子的作用.此化合物表现出微秒级的固态长的荧光寿命,且发绿光.“,”One copper(Ⅰ) cyanide coordination polymer (CuCN)n was synthesized and structurally characterized by single-crystal X-ray diffraction.The title complex has an undulating layer sheets architecture containing 12-member Cu6(CN)6 rings without any other auxiliary ligand.There is a protonated morpholine cation acting as a template and counter-ion in the ring.This compound exhibits long luminescent lifetime in the solid state upper to microsecond order of magnitude and shows a green luminescence emission maxima.