Preparation, Characterization and Dielectric Properties of Ba6Mg0.67Nb9.33O30 Ceramic

来源 :武汉理工大学学报(材料科学版)英 | 被引量 : 0次 | 上传用户:lawrenceccc
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A new niobate Ba6Mg0.67Nb9.33O30 was synthesized in the BaO-MgO-Nb2O5 system by solid state reaction at 1350 ℃ for 48 h . The structure and dielectric properties of Ba6Mg0.67Nb9.33O30 were determined by X-ray powder diffraction, scanning electron microscopy and dielectric measurements. The results show that Ba6Mg0.67 Nb9.33O30 belongs to ferroelectric phase of filled tetragonal tungsten bronze structure at room temperature with unit cell parameters: a = 1.26052(4) nm, c = 0.40045(2) nm, space group P4bm, calculated density 5.707g·cm-3.Ba6Mg0.67Nb9.33O30 belongs to relaxor ferroelectrics undergoing diffusive phase transition,and the transition temperature ( Tc ) is 30 ℃ observed at 10 kHz. At room temperature, Ba6Mg0.67Nb9.33O30ceramic has a high dielectric constant 850 at 1 MHz and a low dielectric loss of 0. 0052.
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