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Compound [C4H3OH][Eu(S2CNC4H3)4].2C4H8O(I), Mr=953,80,monoclinic, P21/n,a = 11,332(3), b= 22,837(5), c= 15.671(2)A,β= 94.93(1)°, V= 4040.2 A3,Z= 4,Dc = 1.567 g/cm3. [C4H8OH][Bu(S2CNC4H8)4] (2),Mr=809.72, monoclinic,P 21/c,a= 12.184(2), b= 15.181(3), c= 18.334(3)A,β=98.57(1)°,V=3353,3 A3,Z = 4, Dc= 1.605 g/cm3. The Eu atom in the anions of 1 and 2 is coordinated by eight S atoms frow four S2CNC4H8 chelate groups in the form of a dodecahedron with approximate D2d symmetry.
Compound [C4H3OH] [Eu (S2CNC4H3) 4] .2C4H8O (I), Mr = 953,80, monoclinic, P21 / n, a = 11,332 (3), b = 22,837 (5), c = 15.671 , β = 94.93 (1) °, V = 4040.2 A3, Z = 4, Dc = 1.567 g / cm3 [C4H8OH] [Bu (S2CNC4H8) 4] (2), Mr = 809.72, monoclinic, a = 12.184 (2), b = 15.181 (3), c = 18.334 (3) A, β = 98.57 (1) °, V = 3353,3 A3, Z = 4, Dc = 1.605 g / cm3. The Eu atom in the anions of 1 and 2 are coordinated by eight S atoms frow four S2CNC4H8 chelate groups in the form of a dodecahedron with approximate D2d symmetry.