Solvent-less synthesis of zinc oxide nanostructures from Zn(salen) as precursor and their optical pr

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ZnO nanoparticles,10-20 nm in size,were synthesized by heat treatment in air at 500℃ for 5 h.,using [N,N-bis(salicylaldehydo) ethylene diamine]zinc(II),i.e.,Zn(salen),as precursor,which was obtained by a solvent-free solid-solid reaction.Heat-treated products were characterized by X-ray diffraction,Fourier transform infrared spectroscopy,scanning electron microscopy,and transmission electron microscopy.Room temperature photoluminescence spectra of ZnO nanostructures are dominated by green emission attributed to oxygen vacancy related donor-acceptor transition. ZnO nanoparticles, 10-20 nm in size, were synthesized by heat treatment in air at 500 ° C for 5 h., Using [N, N- bis (salicylaldehydo) ethylene diamine] zinc (II), ie, Zn as precursor, which was obtained by a solvent-free solid-solid reaction. Heat-treated products were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and transmission electron microscopy. Room temperature photoluminescence spectra of ZnO nanostructures are dominated by green emission attributed to oxygen vacancy related donor-acceptor transition.
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