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  5. Chiral N-phosphonyl imine chemistry:asymmetric additions of glycine enolate to diphenyl diamine-base

Chiral N-phosphonyl imine chemistry:asymmetric additions of glycine enolate to diphenyl diamine-base

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：whlwzn
【摘 要】
：
Diphenyl diamine-based phosphonyl imines attached by the N-isopropyl group in the auxiliary have been synthesized in good yields under convenient reaction condi
【作 者】
：
PINDI Suresh KATTAMURI Padmana 
【机 构】
：
DepartmentofChemistryandBiochemistry
【出 处】
：
中国科学：化学英文版
【发表日期】
：
2010年1期
【关键词】
：
CHIRAL N-phosphonyl IMINE CHIRAL PHOSPHORAMIDE GLYCINE ENOLATE α-β diamino ester 
【基金项目】
：
supported by the National Institutes of Health (Grant Nos.1 RO3 DA026960-01),Robert Welch Foundation (Grant No.D-1361)
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Diphenyl diamine-based phosphonyl imines attached by the N-isopropyl group in the auxiliary have been synthesized in good yields under convenient reaction conditions.These new chiral N-phosphonyl imines can react with glycine enolate smoothly to give chir
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