Synthesis, Crystal Structure and Electrochemistry of Two Complexes (YLn)3+[PW12O40]3-(L=Me2SO, Me2NC

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The reaction of α-H3[PW12O40] with Y(NO3)3 in the presence of DMF or DMSO leads to two complexes with the formulae {Y(DMSO)7}·PW12O40(1) and {[Y(DMF)7]2PW12O40}·PW12O40(2). The crystal structures indicate that complex 1 consists of discrete [YLn
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