【摘 要】
：
A novel 2-D lead-containing hybrid compound, [(PbCl2)(μ-Pyz)1/2]n (Pyz = pyrazine) 1, has been synthesized by the hydrothermal assembly of pyrazine with lead c
【机 构】
：
State Key Laboratory of Structural Chemistry
【基金项目】
：
福建省自然科学基金;国家重点基础研究发展计划(973计划);国家自然科学基金
论文部分内容阅读
A novel 2-D lead-containing hybrid compound, [(PbCl2)(μ-Pyz)1/2]n (Pyz = pyrazine) 1, has been synthesized by the hydrothermal assembly of pyrazine with lead chloride.Elemental analysis and X-ray crystal structure analyses were carried out for the structural determination and characterization of the title compound. Compound 1 crystallizes in orthorhombic,space group Ibam, with a = 19.5558(18), b = 7.1939(6), c = 7.5449(6) (A), V = 1061.44(16) (A)3,C2H2Cl2NPb, Mr= 318.14, Z = 8, Dc= 3.982 g/cm3,μ = 32.63 mm-1, F(000) = 1096.0, R = 0.0368and wR = 0.0901 for 623 observed reflections (1 ＞ 2σ(Ⅰ)).
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