Synthesis and Fluorescence of alt-Copoly[1,4-divinylenebenzene/1,4-bis(dimethylsilylene)benzene]

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Silicon inserted π conjugated copolymer was synthesized by Heck reaction with moderate molecular weight. This silicon containing copolymer is thermally stable to 400 ℃, while emission of this polymer is blue-shifted compared with polyphenylenevinylene greenish emission. It shows potential application as organic emitter in OLED.
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