Syncrude焦化重瓦斯油中甲苯不溶物的分离

来源 :中国化学工程学报 | 被引量 : 0次 | 上传用户:gui_123456
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Toluene insoluble matter (TIM) in coker heavy gas oil (CHGO) from oil sands bitumen is harmful to the downstream hydrotreating, and it may be difficult to be removed by conventional filtration. In order to determine its origin, the TIM must first be separated from CHGO for characterization. Two techniques are described to accomplish this goal. In the ultra-centrifugation approach used in this work, CHGO is blended with a miscible liquid and centrifuged under 366000 G (gravity) force. Through this procedure toluene and hexane diluents yielded TIM contents of 24μg.g-1 and 88μg.g-1 respectively. In an alternative simplified procedure, the initial ultracentrifugation step is omitted. Several different solvents are evaluated for use as diluents but, in each case, toluene is still used in the subsequent washing steps. TIM contents determined by this method range from 23 to about Other conditions, such as diluent-oil ratio, water-oil ratio, mixing time, temperature and water pH value, are also studied.
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