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Two new binuclear copper（Ⅱ） complexes, [Cu（oxpn）CuL]（ClO<sub>4</sub>）<sub>2</sub>, have been synthesizedand characterized, where oxpn is N,N’ bis（3-aminopropyl）oxamido and L is 1,10-phenan-throline （phen） or 5-nitro-1,10-phenanthro