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Four novel transitional metal complexes with 3-(4-pyridly)-4-phenyl-5-sulfhydryl-1,2,4-triazole(HL1)and 3-(3-pyridly)-4-phenyl-5-sulfhydryl-1,2,4-triazole(HL2)were synthesized and characterized by elemental analysis,IR and X-ray diffraction.Complexes 1,3 and 4 have two-dimensional(2-D)neutral rhombohedral grid with a(4,4)topology.In 1,3 and 4,all the metal ions are six-coordinated to four nitrogen atoms of four distinct ligands and two O atoms from water molecules.Complex 2 has tetranuclear Cu4Cl4units which are interconnected by four desulfurization ligands(L1-S)via Cu–N bonds to form a 2-D layer with(4,4)topology.
Four novel transitional metal complexes with 3- (4-pyridly) -4-phenyl-5- sulfhydryl-1,2,4-triazole (HL1) and 3- , 2,4-triazole (HL2) were synthesized and characterized by elemental analysis, IR and X-ray diffraction. Complexes 1, 3 and 4 with two- . In 1,3 and 4, all the metal ions are six-coordinated to four nitrogen atoms of four distinct ligands and two O atoms from water molecules. Complex 2 has tetranuclear Cu4Cl4 units which are interconnected by four desulfurization ligands (L1-S) via Cu-N bonds to form a 2-D layer with (4,4) topology.