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This paper introduces the effects of cell operating temperature, methanol concentration and airflow rate, respectively, on the performance of direct methanol fuel cell (DMFC). A novel method based on fuzzy neural networks identification technique is proposed to establish the performance model of DMFC. Three dynamic performance models of DMFC under the influences of cell operating temperature, methanol concentration, and airflow rate are identified and established separately.Simulation results show that modeling using fuzzy neural networks identification is satisfactory with high accuracy. It is applicable to DMFC control systems.