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通过固相反应,合成了新的配合物六亚甲基四胺锑(Ⅲ)、铋(Ⅲ):SbCl3(C6H12N4)2·H2O(1)、BiCl3(C6H12N4)2·H2O(2).经元素分析、X 射线粉末衍射、远红外光谱和差热 热重分析进行表征,确定了配合物的组成和结构.对XRD谱指标化,确定其晶系和晶胞参数.SbCl3(C6H12N4)2·H2O(1):a=1.2490nm,b=1.4583nm,c=1.6870nm,β=91.78°,V=3.0706nm3;BiCl3(C6H12N4)2·H2O(2):a=1.3250nm,b=1.3889nm,c=1.7449nm,β=98.94°,V=3.1725nm3.
A new complex antimony (Ⅲ) and bismuth (Ⅲ): SbCl3 (C6H12N4) 2 · H2O (1) and BiCl3 (C6H12N4) 2 · H2O (2) were synthesized by solid state reaction Elemental analysis, X-ray powder diffraction, far-infrared spectroscopy and differential thermal gravimetric analysis were used to characterize the composition and structure of the complex. The XRD spectra were normalized to determine the crystal system and unit cell parameters.SbCl3 (C6H12N4) 2 · A = 1.2490 nm, b = 1.4583 nm, c = 1.6870 nm, β = 91.78 °, V = 3.0706 nm3; BiCl3 (C6H12N4) 2 .H2O (2): a = 1.3250 nm, b = , c = 1.7449 nm, β = 98.94 °, V = 3.1725 nm 3.