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硅杂六元环化合物在有机硅化学中是一类重要的小分子环系化合物,广泛应用于有机化学、高分子化学、金属有机化学以及材料化学等领域。本文综述了环上只含有一个硅原子的硅杂六元环化合物的反应,介绍了硅原子上取代基的反应、立体选择性合成、硅原子α位碳原子上的反应、插入反应、环加成反应、Si—C键的切断反应、硅杂苯衍生物合成以及金属配位反应等,并展望了硅杂六元环化合物反应化学的发展方向。
Silicon-based six-membered ring compounds are an important class of small ring systems in organosilicon chemistry. They are widely used in organic chemistry, polymer chemistry, metalorganic chemistry and materials chemistry. This review summarizes the reactions of silicon-containing six-membered ring compounds containing only one silicon atom on the ring. The reactions of substituents on the silicon atom, the stereoselective synthesis, the reaction at the α-position of the silicon atom, the insertion reaction, Si-C bond cleavage reaction, synthesis of silabenzene derivatives and metal coordination reaction, and the development of reaction of silicon six-membered ring compound chemistry are also prospected.