【摘 要】
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T One novel oxamido-bridged trinuclear complex[Cu(CuL)2(ClO4)2]has been synthesized and structurally determined.It crystallizes in the monoclinic system,space g
【机 构】
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Tianjin Key Laboratory of Structure and Performance for Functional Molecule
论文部分内容阅读
T One novel oxamido-bridged trinuclear complex[Cu(CuL)2(ClO4)2]has been synthesized and structurally determined.It crystallizes in the monoclinic system,space group P21/nwith α=10.636(4),b=11.645(4),c=16.038(6)(A),β=91.029(5)°,V=1986.2(12)(A)3,C38H32Cl2Cu3N8O12,Mr=1054.24,Dc=1.763 Mg/m3,/z(MoKα)=1.802 mm-1,F(O00)=1066,Z=2,the final R=0.0328 and wR=0.0882 for 3152 observed reflections.The crystal structure is a hydrogen bonding interactions link the trinuclear fragment to form a 2D supramolecular architecture.Magnetic measurements indicate that the compound is moderately antiferromagnetically coupled.
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