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提出了利用溶剂浮选富集DDTC-Cu(Ⅱ)体系测定水样中痕量铜的方法(DDTC为二乙胺二硫代甲酸钠)。质量浓度的检出限为0.05ng·mL-1,线性范围为0.0~6.0ng·mL-1,测定含Cu(Ⅱ)4.0ng·mL-1的样品,相对标准偏差为0.85%,已用于天然水中Cu(Ⅱ)的测定。
A method for the determination of trace copper in water samples by DDTC-Cu (II) enrichment by solvent flotation was proposed (DDTC is diethylamine sodium dithiocarboxylate). The detection limit of mass concentration was 0.05ng · mL-1, the linear range was 0.0 ~ 6.0ng · mL-1, the sample containing 4.0ng · mL-1 of Cu (Ⅱ) was determined with the relative standard deviation of 0.85%, has been used for determination of Cu (Ⅱ) in natural water.