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研究了表面配合物的热分解动力学问题,计算了 若干MgO的表面Madelung常数,并把H_2C_3O_4-MgO体系的热分解动力学问题转化为均匀表面的迭加问题处理。对于更复杂的体系,基于表面能量的不均匀性,提出了动力学方程。
The thermal decomposition kinetics of the surface complexes was studied. The surface Madelung constants of some MgO were calculated and the thermal decomposition kinetics of H 2 C 3 O 4 -MgO system was transformed into the uniform surface. For more complex systems, based on the inhomogeneous surface energy, a kinetic equation is proposed.