Thermodynamic analysis of the compositional control of inclusions in cutting-wire steel

来源 :International Journal of Minerals Metallurgy and Materials | 被引量 : 0次 | 上传用户:wang9230c
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Data from a thermodynamic database and the calculation software FactSage were used to investigate the phase diagrams of the MnO-CaO-SiO_2-Al_2O_3 system in cutting-wire steel and the effects of oxide components on the low-melting-point(LMP) zone in the corresponding phase diagrams.Furthermore,the activities of oxide components in the quaternary system at an Al_2O_3 content of 25wt%were calculated.The contents of dissolved[Al]and[O]in liquid steel in equilibrium with LMP inclusions in the MnO-CaO-SiO_2-Al_2O_3 system were optimized.The results show that the MnO-CaO-SiO_2-Al_2O_3 system possesses the largest LMP zone(below 1400℃) at an Al_2O_3 content of 25wt%and that the CaO content should be simultaneously controlled in the range of 40wt%to 45wt%.The activities of the oxide components CaO,MnO,and SiO_2 should be restricted in the ranges of 0 to 0.05,0.01 to 0.6,and 0.001 to 0.8,respectively.To obtain LMP inclusions,the[Al]and[O]contents in cutting-wire steel must be controlled within the ranges of 0.5×10~(-6) to 1.0 ×10~(-5) and 3.0 × 10~(-6) to5.0 × 10~(-5),respectively. Data from a thermodynamic database and the calculation software FactSage were used to investigate the phase diagrams of the MnO-CaO-SiO_2-Al_2O_3 system in cutting-wire steel and the effects of oxide components on the low-melting-point (LMP) zone in the corresponding phase diagrams. Ferrthermore, the activities of oxide components in the quaternary system at an Al 2 O 3 content of 25 wt% were calculated. The contents of dissolved [Al] and [O] in liquid steel in equilibrium with LMP inclusions in the MnO-CaO -SiO_2-Al_2O_3 system were optimized. The results show that the MnO-CaO-SiO_2-Al_2O_3 system possesses the largest LMP zone (below 1400 ℃) at an Al_2O_3 content of 25wt% and that the CaO content should be simultaneously controlled in the range of 40wt% to 45wt%. The activities of the oxide components CaO, MnO, and SiO_2 should be restricted in the ranges of 0 to 0.05, 0.01 to 0.6, and 0.001 to 0.8, respectively.To obtain LMP inclusions, the [Al] and [O] contents in cutting-wire steel must be controlled within the ranges of 0.5 × 10 -6 to 1.0 × 10 -5 and 3.0 × 10 -6 to 5.0 × 10 -5, respectively.
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