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Two unusual complexes[Cd2(Do)4(H2O)2Cl](PW12O40)2H2O(1)and[Ag4(Do)6(PW12O40)][Ag(Do)2]2(PW12O40)2H2O(2)were hydrothermally synthesized by the combination of two different metallic salts,Keggin-type polyoxometalate and 1,10-phen-5,6-dione(Do),and character