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有机硫稀土配合物是以有机硫软碱配体与稀土离子配位形成的一类化合物,由于有机硫稀土配合物具有的一些可能的特殊性能和应用,近年来有机硫稀土配合物的研究已成为稀土配位化学研究的重要领域之一。本文综述了二硫代(氨基)甲酸、二硫代磷酸、硫脲、硫醇等有机硫稀土配合物的合成、结构与性质的研究进展,系统综述了有机硫稀土配合物在纳米稀土硫化物制备、橡胶硫化、新型摩擦剂、生物抗菌剂、催化剂、单分子磁性、电致发光材料、镧系元素萃取分离等方面的潜在应用。
Organosulfur Rare Earth Complexes is a kind of compound formed by complexing organosulfur soft base ligands with rare earth ions. Due to some possible special properties and applications of organic sulfur rare earth complexes, researches on organosulfur Rare Earth Complexes Become one of the important fields of rare earth coordination chemistry research. In this paper, the synthesis, structure and properties of organosulfur rare earth complexes, such as dithio (amino) formic acid, dithiophosphoric acid, thiourea and mercaptan, are summarized. The recent progress in the synthesis, structure and properties of organosulfur rare earth complexes Preparation, rubber vulcanization, new type of friction agent, biological antibacterial agent, catalyst, single molecule magnetism, electroluminescent material, and lanthanide extraction and separation.