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在pH为3的醇水混合溶剂中合成了β- 丙氨酸、1, 10 -邻菲咯林、铜的三元配合物,测定了配合物的晶体结构。晶体属单斜晶系,Pī空间群,晶胞参数a=1. 0045(2)nm, b=1. 2132(2)nm, c=0. 71682(14)nm, α=93. 88(3)°, β= 94. 31 ( 3 )°, γ= 99. 81 ( 3 )°, V=0. 8555 ( 3 )nm3, Z=2, Dc=1. 669Mg·m-3, μ=1. 326mm-1, F(000) =442, R=0. 0457, Rw=0. 1179。配合物中铜离子的配位数为5,分子间通过氢键构成三维网状结构。
The ternary complexes of β - alanine, 1,10 - phenanthroline and copper were synthesized in a mixed solvent of alcohol and water at pH 3. The crystal structure of the complex was determined. The crystal is monoclinic, Pī space group, the unit cell parameters a = 1. 0045 (2) nm, b = 1.2132 (2) nm, c = 0. 71682 (14) nm, α = 93.88 3) °, β = 94.31 (3) °, γ = 99. 81 (3) °, V = 0.8555 (3) nm3, Z = 2, Dc = 1.669Mg · m-3, μ = 1. 326mm-1, F (000) = 442, R = 0. 0457, Rw = 0.1179. The coordination number of copper ion in the complex is 5, and the three-dimensional network structure is formed by the hydrogen bonds between the molecules.