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本文综述了两亲性杯芳烃分子在不同维数下组装研究的进展,主要包括零维组装(囊泡、胶束、树枝状分子和分子箱)、一维组装(纳米管,纳米线及纤维)和二维组装(LB膜、超薄分离膜及界面组装);探讨了不同维数下组装体的形成机理和驱动力,主要包括氢键作用、金属配位作用、静电作用、包结络合作用以及疏水相互作用;控制和调节不同维数下组装体的转变,有助于组装体材料在许多方面的应用。
This review summarizes advances in the assembly of amphipathic calixarene molecules at different dimensions, including zero-dimensional assembly (vesicles, micelles, dendrimers and molecular boxes), one-dimensional assembly (nanotubes, nanowires and fibers ) And two-dimensional assembly (LB film, ultra-thin separation membrane and interface assembly). The formation mechanism and driving force of assemblies under different dimensions were discussed, including hydrogen bonding, metal coordination, electrostatic interaction, Cooperation and hydrophobic interaction; control and adjust the assembly of different dimensions of the transformation, contribute to the assembly of materials in many ways.