α-磷酸氢锆α-Zr(HPO4)2.H2O是一类典型的层状结构的多功能材料,本文首次报道了非芳香杂环化合物六氢吡啶对α-ZrP的插层反应。用元素分析,红外光谱(IR)、X射线粉末衍射(XRD)和TG-DSC热分析对α-ZrP的插层复合物α-ZrP-HHP进行了表征。研究表明,六氢吡啶的插入使层间距增大0.59nm,插入的六氢吡啶客体分子在主体底物中形成双层分子,一个α-ZrP分子刚好接受一个六氢吡啶分子。 α-Zr (α-Zr (HPO4)) 2.H2O is a kind of typical multi-functional material with layered structure. For the first time, the intercalation reaction of non-aromatic heterocyclic compounds with α-ZrP was reported. The α-ZrP-HHP intercalation complex of α-ZrP was characterized by elemental analysis, infrared spectroscopy (IR), X-ray powder diffraction (XRD) and TG-DSC. Studies have shown that the insertion of the piperidine increases the interlayer spacing by 0.59 nm. The inserted PDH guest molecules form a double-layered molecule in the host substrate. An α-ZrP molecule happens to accept only one piperidine molecule.