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设计合成了(E)-3-[2-(8-羟基喹啉基)-乙烯基]-N-对甲苯基咔唑8和(E)-3-[2-(8-羟基喹啉基)-乙烯基]-N-对甲氧苯基咔唑9及它们相应金属铜配合物10和11四个新的化合物,用UV-Vis,FT-IR,ESI-MS,FAB-MS,1HNMR,13C NMR和元素分析确认了化合物的结构.热重分析实验表明金属铜配合物10和11有很好的热稳定性,并把这两个金属铜配合物做成有机单层发光器件,都能发出稳定的蓝绿光.这两个发光器件的最大亮度分别是345 cd/m2,325 cd/m2,最大电流效率分别为0.68 cd.A-1,1.53 cd.A-1.
(E) -3- [2- (8-hydroxyquinolinyl) -vinyl] -Np-tolylcarbazole 8 and (E) -3- [2- ) -vinyl] -N-p-methoxyphenylcarbazole 9 and their corresponding metal copper complexes 10 and 11 were characterized by UV-Vis, FT-IR, ESI-MS, FAB-MS, , 13C NMR and elemental analysis confirmed that the structure of the compounds.Thermal gravimetric analysis experiments show that the metal copper complexes 10 and 11 have good thermal stability and the two metal copper complexes made of organic single-layer light-emitting devices are Can emit a stable blue-green light.The maximum brightness of these two light-emitting devices were 345 cd / m2, 325 cd / m2, the maximum current efficiency was 0.68 cd.A-1, 1.53 cd.A-1.