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Fe_2OSsN_2C_(52)H_(70),Mr=1043.23,monoclinic, P21/a, a=18.121(3), b=15.249(3), c=20.369(4)A,β=102.49(8)°,V=5495(1)A3, Z=4, Dc=1.261g.cm-3,MoKα(λ =0.710691), μ=17.816mm-1, F(000)=2208. R=0.073 for 4374 observed reflections with I≥3.0σ(I). The structure of the anion contains a linear Fe-O-Fe unit, with mean Fe-O distance of 1.766(2)A. The coordination geometry about each iron atom is close to tetrahedral with the angles O-Fe-S and S-Fe-S being 115.3° and 103.1°, respectively.
(2) Fe 2OSsN_2C_ (52) H_ (70), Mr = 1043.23, monoclinic, P21 / a, a = 18.121 3, b = 15.249 3, c = 20.369 4, A = = 5495 (1) A3, Z = 4, Dc = 1.261 g.cm-3, MoKα (λ = 0.710691), μ = 17.816 mm -1, F (000) = 2208. R = 0.073 for 4374 observed reflections with I ≥3.0σ (I). The structure of the anion contains a linear Fe-O-Fe unit with mean Fe-O distance of 1.766 (2) A. The coordination geometry about each iron atom is close to tetrahedral with the angles O -Fe-S and S-Fe-S being 115.3 ° and 103.1 °, respectively.