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采用实验研究和理论分析相结合的方法研究了体积分数为0.15~3%超低浓度甲烷在0.5%Pd/Al_2O_3(质量分数)催化颗粒鼓泡流态化状态下的催化燃烧特性,根据其在密相区和稀相区的流动及反应特点,建立了低浓度甲烷催化燃烧反应模型,并在不同温度、进气甲烷浓度、床层高度等工况下进行了模型预测及与实验数据的对比分析。研究结果表明:考虑了稀相区中催化颗粒飞溅,模型计算数据与实验数据吻合较好,误差在5%以内;反应器出口无量纲甲烷浓度随着床层温度的升高、进气甲烷浓度的降低以及床层高度的升高而降低;通过与活塞流,全混流反应模型的对比分析,进一步验证了所建立的数学模型能够较好地反映超低浓度甲烷在鼓泡流态化状态下的催化燃烧特性。
The catalytic combustion characteristics of 0.5% Pd / Al_2O_3 (mass fraction) catalytic particles under the conditions of bubbling fluidization with ultra-low methane concentration of 0.15 ~ 3% were studied by experimental study and theoretical analysis. Dense phase zone and dilute zone flow and reaction characteristics, the establishment of a low concentration of methane catalytic combustion reaction model, and at different temperatures, intake methane concentration, bed height and other conditions under the model prediction and comparison with the experimental data analysis. The experimental results show that the calculated particle size is in good agreement with the experimental data, and the error is less than 5%. Considering the spattering of catalytic particles in the dilute phase, the calculated data agree well with the experimental data. With the increase of bed temperature, And the height of the bed increases. The comparison and analysis with the plug flow and the full mixed flow model further verify that the established mathematical model can better reflect the low concentration of methane in the bubbling fluidized state The catalytic combustion characteristics.