The sluggish redox kinetics and shuttle effect of soluble polysulfides intermediate primarily restrict the electrochemical performance of lithium-sulfur (Li-S) batteries.To address this issue,rational design of high-efficiency sulfur host is increasingly demanded to accelerate the polysulfides conversion during charge/discharge process.Herein,we propose a macro-mesoporous sulfur host (Co@NC),which comprises highly dispersed cobalt nanoparticles embedding in N-doped ultrathin carbon nanosheets.Co@NC is simply synthesized via a carbon nitride-derived pyrolysis approach.Owing to the highly conductive graphene-like matrix and well defined porous structure,the designed multifunctional Co@NC host enables rapid electron/ion transport,electrolyte penetration and effective sulfur trapping.More significantly,N heteroatoms and homogeneous Co nanocatalysts in the graphitic carbon nanosheets could serve as chemisorption sites as well as electrocatalytic centers for sulfur species.These Co-N active sites can synergistically facilitate the redox conversion kinetics and mitigate the shuttling of polysulfides,thus leading to improved electrochemical cycling performance of Li-S batteries.As a consequence,the S/Co@NC cathode demonstrates high initial specific capacity (1505 mA h g-1 at 0.1 C) and excellent cycling stability at 1 C over 300 cycles,giving rise to a capacity retention of 91.7％ and an average capacity decline of 0.03％ cycle-1.