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用脉冲法研究了己烷各异构体在自制M_(23)型催化剂上的反应机理和动力学。结果表明,己烷各异构体在该催化剂上的反应活性次序为3MP～ZMP～2,3DMB>nH>2,2DMB。建立了己烷异构化反应的三族反应网络,并Wei-Prater方法求得了该反应网络中各步反应的相对反应速度常数和表观活化能。
The reaction mechanism and kinetics of hexane isomers on home-made M_ (23) catalyst were studied by pulse method. The results showed that the order of reactivity of hexane isomers was 3MP ~ ZMP ~ 2,3DMB> nH> 2,2DMB. The three-group reaction network of hexane isomerization was established. The relative reaction rate constants and apparent activation energies of each reaction in the reaction network were calculated by Wei-Prater method.