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合成了N-氧化吡啶-2-甲醛缩二胍合铜的新型配合物,通过元素分析、红外光谱、电导、热重测定,对配合物进行了表征,并测定了配合物的变温磁化率,表明双核配合物中铜离子间存在反铁磁性交换作用.
The novel complexes of pyridine-2-carboxaldehydedecanediamine were synthesized. The complexes were characterized by elemental analysis, FTIR, conductivity and thermogravimetric analysis. The temperature-dependent susceptibility of the complexes was also determined. It shows that there is antiferromagnetic exchange between copper ions in binuclear complex.