Influence of structural and lithological controls of various drainage patterns and their stream orientations(for 2nd, 3rd and 4th order steams) were identified to evaluate the direction and controlling factors of drainage network. To investigate the prospect of groundwater, hydrogeomorphological features of river basin viz. Mulki-Pavanje were identified and mapped. To evaluate the characteristics of the basin, different morphometric parameters(linear, areal and relief) were computed in sub-basin wise(SB-I to-VII). The linear parameters suggest drainage network is controlled by geomorphology. The form factor(Ff), elongation ratio(Re) and circularity ratio(Rc) suggest that the basin is in an elongated shape. The drainage density(Dd) indicates resistant/permeable strata under medium-dense vegetation with moderate relief. The areal parameters of the sub-basins(except SBI and Ⅲ) indicates moderate ground-slopes associated with moderately permeable rocks, which promote moderate run-off and infiltration. Drainage texture(T) of the whole basin indicates coarse texture while the SB-I, and Ⅲ showing an intermediate texture. The relief parameters namely ruggedness number(Rn) infers low basin relief and poor drainage density. To identify the most deficit/surplus zones of groundwater suitable weightages were assigned to the hydrogeomorphological units and morphometric parameters. The study reveal that the basin manifest that SB-Ⅲ shall be most deficit zone of groundwater, whereas SB-VII, VI and V are found to show increase in groundwater potentiality. Groundwater prospect area in this basin is estimated to be 7% area under poor, 44% area under moderate and 49% area under good to excellent. This paper demonstrated the potential application of geographical information system(GIS) techniques to evaluate the groundwater prospect in absence of traditional groundwater monitoring data. Influence of structural and lithological controls of various drainage patterns and their stream orientations (for 2nd, 3rd and 4th order steams) were identified to evaluate the direction and controlling factors of drainage network. To investigate the prospect of groundwater, hydrogeomorphological features of river basin viz To evaluate the characteristics of the basin, different morphometric parameters (linear, areal and relief) were computed in sub-basin wise (SB-I to-VII). The linear parameters suggest drainage network is controlled by geomorphology. The form factor (Ff), elongation ratio (Re) and circularity ratio (Rc) suggest that the basin is in an elongated shape. The drainage density (Dd) indicates resistant / permeable strata under medium- dense vegetation with moderate relief. The areal parameters of the sub-basins (except SBI and Ⅲ) indicate moderate ground-slopes associated with moderately permeable rocks, which promote moderate run-off and The relief parameters of ruggedness number (Rn) infers low basin relief and poor drainage density. To identify the most deficit / surplus zones of groundwater suitable weightages were assigned to the hydrogeomorphological units and morphometric parameters. The study reveals that the basin manifest that SB-Ⅲ shall be most deficit zone of groundwater, but SB-VII, VI and V are found to show increase in Groundwater potential area in this basin is estimated to be 7% area under poor, 44% area under moderate to 49% area under good to excellent. This paper demonstrated the potential application of geographical information system (GIS) techniques to evaluate the groundwater prospect in absence of traditional groundwater monitoring data.