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烯酮与亚甲胺之间发生环加成反应可以生成氮杂环丁酮: 关于这个反应的机理,目前还未见报导。我们用从头计算分子轨道法,在RHF/3-21G的水平,研究了上述反应的机理,同时采用内禀反应坐标法(IRC)得出了反应途径。所得结果说明了此反应不存在中
Cyclic addition reaction between enone and methylene amine can generate azetidinone: There is no report on the mechanism of this reaction. We used the ab initio molecular orbital method to study the mechanism of the above reaction at the level of RHF / 3-21G, and the reaction pathway was obtained by the intrinsic reaction coordinate method (IRC). The result shows that this reaction is absent