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我们采用流动放电—化学发光光子计数方法测定O(~3p)原子与CH_3COCH_2CH(CH_3)_2反应在303-503K范围内反应速率常数,得出了反应速率常数与温度关系的Arrhenius参数。实验装置和数据处理方法在前文中已作过详细描述。现将各反应温度下测得的O(~3p)和CH_3COCH_2CH(CH_3)_2反应的假一级反应速率常数k’和二级反应的速率常数k的详细结果列
The Arrhenius parameters of reaction rate constant and temperature were obtained by the flow-discharge chemiluminescence photon counting method. The reaction rate constants of reaction between O (~ 3p) atoms and CH_3COCH_2CH (CH_3) _2 in the range of 303-503K were obtained. Experimental setups and data processing methods have been described in detail in the previous section. Detailed results of the pseudo first-order reaction rate constant k ’and the second-order rate constant k of the reaction of O (~ 3p) and CH_3COCH_2CH (CH_3) _2 at each reaction temperature