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5. Quantum chemical study on asymmetric catalysis reduction of imine

Quantum chemical study on asymmetric catalysis reduction of imine

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：dgfm1028

【摘 要】

：

The quantum chemical method is employed to study the enantioselective reduction of imine with borane catalyzed by chiral oxazaborolidine. All the structures are

【作 者】

：

LI Ming (李明) TIAN Anmin (田安民) 

【机 构】

：

DepartmentofChemistry

【出 处】

：

中国科学：化学英文版

【发表日期】

：

2003年2期

【关键词】

：

CHIRAL oxazaborolidine imine ASYMMETRIC CATALYSIS reduction DFT. chiral oxaza 

【基金项目】

：

教育部重点科研项目

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The quantum chemical method is employed to study the enantioselective reduction of imine with borane catalyzed by chiral oxazaborolidine. All the structures are optimized completely at the B3LYP/6-31G(d) level. The catalysis property of oxazaborolidine is

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