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用1,3-二(4-吡啶基)丙烷、对苯二甲酸和去离子水在413K下通过水热反应法得到了标题化合物(C13H14N2).(C8H6O4).该化合物晶体属于三斜晶系,空间群为P墿,晶胞参数为a=0.95267(19)nm,b=1.1927(2)nm,c=1.6959(3)nm,α=96.40(3)°,β=98.12(3)°,γ=101.52(3)°,Z=2.单晶衍射结果表明标题化合物由对苯二甲酸分子和1,3-二(4-吡啶基)丙烷通过两种类型的分子间π-π堆积作用以及O—H…N氢键作用构成.同时,还对标题化合物进行了元素分析和红外测试.
The title compound (C13H14N2). (C8H6O4) was obtained from 1,3-bis (4-pyridyl) propane, terephthalic acid and deionized water at 413K by a hydrothermal reaction. This compound belongs to the triclinic system , The space group is P 墿 and the unit cell parameters are a = 0.95267 (19) nm, b = 1.1927 (2) nm, c = 1.6959 , γ = 101.52 (3) °, Z = 2. The single crystal diffraction results show that the title compound consists of terephthalic acid molecules and 1,3-bis (4-pyridyl) propane through two types of intermolecular π-π stacking As well as the O-H ... N hydrogen bonding.At the same time, the title compound was also subjected to elemental analysis and infrared testing.