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The mixed spinel ferrite system Mg0.95Mn0.05Fe2-2xTi2xO4(0≤x≤0.7) was synthesized by the conventional solid-state reaction technique. The effect of Ti4+ doping was studied by using the M(o)ssbauer spectroscopy measurements at room temperature. From the analysis of the M(o)ssbauer spectra, it is observed that s-electron density, electric field gradient (EFG), quadrupole coupling constant (QCC) and the net hyperfine magnetic fields acting on the M(o)ssbauer nuclei-FeA3+ and FeB3+ change with the increase of Ti4+ doping in Mg0.95Mn0.05Fe2O4. The hyperfine magnetic field decreases with the increase of Ti4+ doping.