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合成了两个含邻甲氧基苯甲醛Schiff碱配体的单核过渡金属配合物:Ni(C15H13N2O3)2(1)和Zn(C15H13N2O3)2(2)。采用元素分析和单晶X-射线衍射对制备的晶体进行了结构表征。结构分析表明,这两个配合物属于异质同晶,晶体属四方晶系,空间群为P41212,Z=4。镍原子和锌原子都形成了扭曲的八面体配位构型。配体的酚氧原子(O1和O1A)未与金属原子配位,而甲氧基的氧原子(O3和O3A)却与金属原子配位。
Two mononuclear transition metal complexes containing o-methoxybenzaldehyde Schiff base ligands were synthesized: Ni (C15H13N2O3) 2 (1) and Zn (C15H13N2O3) 2 (2). The prepared crystals were characterized by elemental analysis and single crystal X-ray diffraction. Structural analysis shows that these two complexes are isomorphic and the crystal belongs to tetragonal system with space group P41212 and Z = 4. Nickel and zinc atoms form a distorted octahedral coordination structure. The phenolic oxygen atoms (O1 and O1A) of the ligand are not coordinated with the metal atoms, while the oxygen atoms of the methoxy group (O3 and O3A) are coordinated with the metal atoms.