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本文报道了11种1,3,2-二氮磷杂环戊烷衍生物的化学电离质谱(CIMS),对热不稳定的化合物采用了解吸化学电离技术(DCI),着重探讨了三价磷和五价磷化合物质谱的差异及均三氮苯取代基的引入对质谱行为的影响;对该类化合物的CIMS和EIMS进行了比较。
In this paper, chemical ionization mass spectrometry (CIMS) of 11 kinds of 1,3,2-diazaphosphorin derivatives was reported. Desorption chemical ionization (DCI) was applied to the thermally unstable compounds. The effects of trivalent phosphorus And the difference of mass spectra of pentavalent phosphorus compounds and the effect of the introduction of the mesitylbenzenes on mass spectrometry behavior were compared. The CIMS and EIMS of these compounds were compared.